nonan-1-ol
CAS No.: 143-08-8 Formula: C9H20O Molecular Weight: 144.25400
Search Suppliers

nonan-1-ol

CAS No.: 143-08-8 Formula: C9H20O Molecular Weight: 144.25400
Suppliers: All (111) China Suppliers (61) Price Available (21) Contractor (1)

Description

1-Nonanol[pronunciation?] is a straight chain fatty alcohol with nine carbon atoms and the molecular formula CH3(CH2)8OH. It is a colorless to slightly yellow liquid with a citrus odor similar to citronella oil.
Nonanol occurs naturally in the orange oil. The primary use of nonanol is in the manufacture of artificial lemon oil. Various esters of nonanol, such as nonyl acetate, are used in perfumery and flavors.

Properties

Appearance & Physical State
colourless to light yellow liquid
Density
0.827
Boiling Point
213-215ºC
Melting Point
-5ºC
Flash Point
74ºC
Refractive Index
1.4324-1.4344
Water Solubility
1 g/L (20 ºC)
Stability
Stable. Combustible. Incompatible with strong oxidizing agents.
Vapor Density
5 (vs air)
Vapor Pressure
13 mm Hg ( 104 °C)

Safety Info

RTECS
RB1575000
Hazard Class
9
Safety Statements
S29-S61
HS Code
2905199090
WGK Germany
2
Packing Group
III
RIDADR
UN 3082
Risk Statements
R20; R51/53
Hazard Codes
Xn; N
Signal Word
Warning
Hazard Declaration
H319; H412
Symbol
GHS07
Caution Statement
P273; P305 + P351 + P338
SDS 1.0 Expand

SDS 1.0

Collapse
Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name
nonan-1-ol

1.2 Other means of identification

Product number
-
Other names
1-Nonanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses
For industry use only. Fragrances
Uses advised against
no data available

1.4 Supplier's details

Company
MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address
Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone
+86(21)64956998
Fax
+86(21)54365166

1.5 Emergency phone number

Emergency phone number
+86-400-6021-666
Service hours
Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Eye irritation, Category 2

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H319 Causes serious eye irritation

H412 Harmful to aquatic life with long lasting effects

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P273 Avoid release to the environment.

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

Storage

none

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
nonan-1-ol
nonan-1-ol
143-08-8
none
100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

Liquid irritates eyes. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Basic Treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . Monitor for pulmonary edema and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Higher alcohols (>3 carbons) and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Fire Extinguishing Agents Not to Be Used: Water may be ineffective Fire Extinguishing Agents: Alcohol foam, dry chemical, or carbon dioxide (USCG, 1999)

5.2 Specific hazards arising from the chemical

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

AEROBIC: Nonyl alcohol degraded fast in aerobic biodegradation screening tests(1-3). In one 5-day BOD test using acclimated mixed cultures, 47.9% of theoretical BOD was consumed(1). In the other test which used an activated sludge inoculum, nonyl alcohol's half-life was 1.2 days(SRC), calculated from a biodegradation rate of 2.36X10-2/hr(3). In a third test, 62% of its theoretical BOD in a grab sample of freshwater incubated at 18-19°C was expended in 4 days(2).

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state
colourless to light yellow liquid
Colour
Colorless to yellowish liquid
Odour
Floral odor
Melting point/ freezing point
-90°C(lit.)
Boiling point or initial boiling point and boiling range
215°C(lit.)
Flammability
no data available
Lower and upper explosion limit / flammability limit
no data available
Flash point
98°C
Auto-ignition temperature
no data available
Decomposition temperature
no data available
pH
no data available
Kinematic viscosity
11.7 centapoise at 20°C
Solubility
In water:1 g/L (20 ºC)
Partition coefficient n-octanol/water (log value)
log Kow = 3.77
Vapour pressure
13 mm Hg ( 104 °C)
Density and/or relative density
0.827g/mLat 25°C(lit.)
Relative vapour density
5 (vs air)
Particle characteristics
no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

NONANOL is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

When heated to decomposition it emits acid smoke and irritating fumes.

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat oral 3.56 g/kg
  • Inhalation: LC50 Mouse inhalation 5500 mg/cu m/2 hr
  • Dermal: no data available
  • Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    no data available

    Reproductive toxicity

    no data available

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    12.Ecological information

    12.1 Toxicity

  • Toxicity to fish: LC50 Pimephales promelas (Fathead minnow, weight 0.12 g) 5.7 mg/L 96 hr flow-through bioassay, water hardness 45.5 mg/L CaCO3, temp: 25 +/- 1°C, pH 7.5, dissolved oxygen >60% of saturation
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available
  • 12.2 Persistence and degradability

    AEROBIC: 1-Nonanol degraded fast in aerobic biodegradation screening tests(1-3). In one 5-day BOD test using acclimated mixed cultures, 47.9% of theoretical BOD was consumed(1). In the other test which used an activated sludge inoculum, 1-nonanol's half-life was 1.2 days(SRC), calculated from a biodegradation rate of 2.36X10-2/hr(2). In a third test, 62% of its theoretical BOD in a grab sample of freshwater incubated at 18-19°C was expended in 4 days(3).

    12.3 Bioaccumulative potential

    An estimated BCF of 160 was calculated for 1-nonanol(SRC), using a log Kow of 3.77(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is high(SRC), provided the compound is not metabolized by the organism(SRC).

    12.4 Mobility in soil

    An estimated BCF of 160 was calculated for 1-nonanol(SRC), using a log Kow of 3.77(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is high(SRC), provided the compound is not metabolized by the organism(SRC).

    12.5 Other adverse effects

    no data available

    13.Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    14.Transport information

    14.1 UN Number

    ADR/RID: Not dangerous goods.
    IMDG: Not dangerous goods.
    IATA: Not dangerous goods.

    14.2 UN Proper Shipping Name

    ADR/RID: unknown
    IMDG: unknown
    IATA: unknown

    14.3 Transport hazard class(es)

    ADR/RID: Not dangerous goods.
    IMDG: Not dangerous goods.
    IATA: Not dangerous goods.

    14.4 Packing group, if applicable

    ADR/RID: Not dangerous goods.
    IMDG: Not dangerous goods.
    IATA: Not dangerous goods.

    14.5 Environmental hazards

    ADR/RID: no
    IMDG: no
    IATA: no

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    no data available

    15.Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    nonan-1-ol
    nonan-1-ol
    143-08-8
    none
    European Inventory of Existing Commercial Chemical Substances (EINECS)
    Listed.
    EC Inventory
    Listed.
    United States Toxic Substances Control Act (TSCA) Inventory
    Listed.
    China Catalog of Hazardous chemicals 2015
    Not Listed.
    New Zealand Inventory of Chemicals (NZIoC)
    Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS)
    Listed.
    Vietnam National Chemical Inventory
    Not Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)
    Listed.

    16.Other information

    Information on revision

    Creation Date
    Aug 10, 2017
    Revision Date
    Aug 10, 2017

    Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%
  • References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

  • Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
    MSDS Expand
    1H NMR : 90 MHz in CDCl3Expand

    NMR Spectrum 1H NMR : 90 MHz in CDCl3

    Collapse

    C9 H20 O 0.04 ml : 0.5 ml CDCl3
    1-nonanol

    Assign. Shift(ppm)
    A 3.617
    B 1.73
    C 1.56
    D 1.28
    E 0.89

    IR : liquid filmExpand
    Mass Expand
    Raman : 4880 A,200 M,liquidExpand
    Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
    Oral
    LD50 - Lethal dose, 50 percent kill
    Rodent - rat
    3560 mg/kg
    1.Details of toxic effects not reported other than lethal dose value
    Intraperitoneal
    LD50 - Lethal dose, 50 percent kill
    Rodent - rat
    800 mg/kg
    1.Details of toxic effects not reported other than lethal dose value
    Oral
    LD50 - Lethal dose, 50 percent kill
    Rodent - mouse
    6400 mg/kg
    1.Details of toxic effects not reported other than lethal dose value
  • Recommended Suppliers
  • Fo shan xin hang sheng wu ke ji you xian gong si

    CHINA

    Purity: 99%

    Lead Time: 2 Day(s)

    Price: Min $48.33 /kg

  • Shanghai Dingsheng Chemical Technology Co., Ltd.

    CHINA

    Purity: ≥98%

    Lead Time: 7 Day(s)

    Price: Min $24 /g

  • Shanghai Xinyu Biological Technology Co., Ltd.

    CHINA

    Purity: 99%

    Lead Time: 2 Day(s)

    Price: Min $100 /ml

  • Shanghai Chengshao Biological Technology Co., Ltd.

    CHINA

    Purity: 99%

    Lead Time: 7 Day(s)

    Price: Min $43.08 /ml

  • Jiangxi Jianglan Pure Biological Reagent Co., Ltd.

    CHINA

    Purity: 99%

    Lead Time: 3 Day(s)

    Price: Min $157 /ml

  • Suzhou Haolu Biological Technology Co., Ltd.

    CHINA

    Purity: 99%

    Lead Time: 3 Day(s)

    Price: -

  • Tai'an Jia Ye Biological Technology Co.,Ltd

    CHINA

    Purity: 99%

    Lead Time: 2 Day(s)

    Price: -

  • Chengdu Changzheng Glass Co.,Ltd.

    CHINA

    Purity: 96%

    Lead Time: 5 Day(s)

    Price: -

  • Shandong Xiaoye Chemical Co., Ltd.

    CHINA

    Purity: 98%

    Lead Time: 0 Day(s)

    Price: -

  • Henan Coreychem Co.,Ltd

    CHINA

    Purity: 98%

    Lead Time: 2-3 Day(s)

    Price: -

  • More Suppliers>>
    Other items you might be interested in
    Category in MOLBASE